Anion Resin Filter Cartridge for Tannin Reduction, Size - 20" x 4.5"

20" Big Blue Anion Resin Tannin Reduction Filter

Introducing the 20" Big Blue Anion Resin Filter designed for effective Tannin Reduction. This filter utilizes food-grade strong base anion resin to efficiently decrease and eliminate tannins and nitrates from your incoming water. If you're dealing with well water or experiencing a persistent brownish discoloration that standard sediment or Iron/Manganese filters can't address, the anion filter may be the ideal solution for your needs.

WHAT IS TANNIN?

• Tannins are large organic compounds found in plants, particularly in the bark, leaves, and fruits of certain trees, and to a lesser extent in animals.
• These astringent and bitter-tasting polyphenols bind and precipitate proteins and vary in structure depending on the local vegetation.
• In water treatment, tannins can cause discoloration, and a bitter taste, and reduce R.O. system effectiveness, impacting water quality.
• It is crucial to remove tannins from water used in R.O. systems with pH 6, and anion exchange resins can be effective for this purpose.

WHAT IS NITRATE?

• Nitrates are chemical salts naturally found in mineral deposits and commonly used in fertilizers.
• Long-term nitrate exposure can lead to kidney damage and certain cancers, posing a significant risk to infants and causing conditions like methemoglobinemia.
• The main source of nitrates in water is agricultural run-off entering the local water table.

HOW TO DETERMINE NITRATE PRESENCE IN WATER:

1. Use test kits available online or at home improvement stores to detect nitrates through a color-changing chemical solution.
2. Submit your water for testing in a laboratory, either through municipal health authorities or private labs.
3. Conduct visual inspections for reddish or brownish water or a metallic taste, indicating potential nitrate contamination.

NOTE: We do not provide testing services. It's essential to regularly test your water for safety, especially concerning nitrate exposure's serious health effects, particularly for young children and pregnant women.

If concerned about water quality, take prompt action to address the situation.

TYPICAL PHYSICAL-CHEMICAL CHARACTERISTICS:

* Weight of resin, as supplied, occupying 1 m in a unit after backwashing and draining.

This anion exchange resin is designed for versatile applications, including use in de-ionizing water filtration systems, chemical processing, and scientific settings. Its applications span the production of ultra-pure water, separation of organic substances, the refinement of antibiotic medicines, as well as the separation and extraction of biochemical products.

TANNIN REMOVAL
Experience the benefits of our specially designed water treatment medium that uses anionic resins to remove tannins and other negatively charged ions from your water, providing you with a pure and refreshing drink.

Tannin molecules tend to form anions in water above pH 6 and can be treated with anion exchange resins. Tannins below pH 5 are better treated with activated charcoal.

Using a softener beforehand removes hardness and metals (like iron) that might otherwise foul the anion resin, reducing its ability to remove tannins.

Tannin removal is dependent on the vegetation in a given area and thus the amount and type of resin necessary can vary. If your well water has a slight yellow or brown tint, the addition of one pound per inch in diameter of your media tank will normally make the water clear. If your water is darker, like Ice Tea, you may need as much as two pounds per inch in diameter of your media tank. There are various methods and each one can vary in result; this is why monitoring your water's results is an important factor in determining the desired results you want to achieve.

The "color" or "tannins" are tested by running the water at the well for a minute or two, then taking a sample in a cup or bucket and observing the color IMMEDIATELY before the iron reacts with the air (oxygen).

You only need the extra Tannin removal resin in with your regular softening resins if you have color when the water is first drawn.

CLEANING METHOD
When a tannin color passes through a working unit, an effort should be made to clean the resin. Soda ash (Na₂CO₃) can be added to the brine to aid in cleaning the anion resin. Typically, 0.5 to 1 pound of soda ash is added to the brine well. A second regeneration should follow after treating the resin with soda ash to fully convert the resin to the chloride form.

If the soda ash method fails to clean the resin, a chlorine treatment can be used as a last resort. This method is not recommended because it is extremely harsh on the resin. Fill the brine well with four to eight ounces of household bleach and set the system to regenerate. If a chlorine odor is detected in the drain line, shut down the system for one to two hours. After the system has soaked, complete the rest of the regeneration cycle. To eliminate any remaining chlorine, a second regeneration should be performed. Note that ion exchange resin is not chlorine resistant. If this treatment proves unsuccessful, replacement must be considered.

Before attempting any cleaning procedure, regenerate the bed with salt if the unit contains both cation and anion. Due to high pH or oxidation, any metals, such as iron, will precipitate on the cation resin.

SERVICE CYCLE
Tannin removal utilizing anion exchange resins combines both ion exchange and an absorption process. Tannins, having a slight negative charge, are exchanged for chloride in the resin. The regeneration of anion resin involves the use of salt (NaCl). Generally, the resin is brined at a rate of approximately 10 pounds of salt per cubic foot. Regular regeneration is crucial, with a recommended frequency of every two to three days. Notably, the anion resin is less dense than cation resin.

Backwashing of an anion resin should be conducted at a different flow rate compared to a cation-softening resin. A flow rate of about two gpm/sf is recommended for anion backwashing. Frequent regenerations are effective in reducing organic fouling.

Tannin resin is a residual by-product of anion resin, and the amine concentration is typically low, with an odor threshold around 40 parts per billion. Mixing ammonia and chlorine can create an environment that breaks down the resin, elevating the pH due to ammonia. If the Total Dissolved Solids (TDS) levels in the influent water exceed 800 ppm, a salty taste may be detected. The use of Reverse Osmosis (RO) is necessary to reduce TDS and eliminate the salty taste.

OTHER METHODS OF REMOVING TANNINS
Chlorine and other oxidizing agents prove effective in breaking down organic compounds like tannins. Conducting a simple jar test can determine the concentration and required time for oxidizing tannins. Post the retention tank, an activated carbon unit can eliminate chlorine and potentially adsorb other organic compounds in the water. Some types of activated carbon may independently reduce tannins to acceptable levels; for the appropriate carbon type, consult your carbon manufacturer. It's important to note that the reaction between chlorine and tannins may generate carcinogenic trihalomethanes (THMs).

Another successful method for tannin removal is reverse osmosis. However, tannins have a tendency to foul the system's membrane in this process. Installing a whole-house reverse osmosis system for comprehensive water treatment can be quite costly. For more information, consult your local water expert.

SAFETY
Caution should be exercised when handling the corrosive acid and alkali solutions used for regeneration to prevent contact with eyes and skin. Goggles and gloves are recommended throughout the entire process. When utilizing oxidizing agents, follow necessary safety precautions to prevent accidents and damage to the resin.

STORAGE
Ion exchange resins should be stored in a cool, shaded place, maintaining a moist environment. The recommended temperature range is between 20 and 40 degrees Celsius. Regularly inspect the resin, add clean demineralized water if needed, and ensure it remains completely moist. Never allow the resin to dry out. Always store the resin drum in the shade.

MAIN PURPOSE
Primarily used for water purification, wastewater treatment, biological products, and the hydrometallurgy of tungsten and molybdenum extraction.

OTHER USES
Additional applications include water softening, desalination of water preparation, preparation of pure water, and high water. Also employed in amino acid extraction and purification, extraction and purification of antibiotics, extraction and removal of heavy metal ions, separation and purification of rare earth elements, and organic synthesis reactions such as hydrolysis and acid esterification catalyst.

SPECIFICATIONS

• Size: 4.5" x 19 7/8", designed to fit Big Blue filter housings
• Resin Content: Contains 5.5-6.5 lbs of resin, depending on the media
• Operating Temperature Range: 40°F-125°F
• Operating Pressure Range: 40-80 PSI
• Minimum Operating Pressure: Maintain 60 PSI to avoid a drop in home water pressure

All filters are individually wrapped; store the product in a closed bag and keep it moist to prevent dryness. Avoid direct sunlight, and store the product at room temperature (40 to 75 Fahrenheit).

Caution: To prevent rapid buildups in the pre-woven filter and ensure the Nitrate filter's longer lifespan without quick clogging and a subsequent drop in pressure throughout your entire home, always install this filter after the sediment filter.

Additionally, it is recommended to follow this filter with either a CTO or GAC carbon filter to effectively combat any unpleasant odors that may arise during the Tannin-to-Chloride exchange. Without a carbon filter after the Tannin filter, there is no effective way to address the issue of foul odors.

20" Big Blue Anion Resin Tannin Reduction Filter

Introducing the 20" Big Blue Anion Resin Filter designed for effective Tannin Reduction. This filter utilizes food-grade strong base anion resin to efficiently decrease and eliminate tannins and nitrates from your incoming water. If you're dealing with well water or experiencing a persistent brownish discoloration that standard sediment or Iron/Manganese filters can't address, the anion filter may be the ideal solution for your needs.

WHAT IS TANNIN?

• Tannins are large organic compounds found in plants, particularly in the bark, leaves, and fruits of certain trees, and to a lesser extent in animals.
• These astringent and bitter-tasting polyphenols bind and precipitate proteins and vary in structure depending on the local vegetation.
• In water treatment, tannins can cause discoloration, and a bitter taste, and reduce R.O. system effectiveness, impacting water quality.
• It is crucial to remove tannins from water used in R.O. systems with pH 6, and anion exchange resins can be effective for this purpose.

WHAT IS NITRATE?

• Nitrates are chemical salts naturally found in mineral deposits and commonly used in fertilizers.
• Long-term nitrate exposure can lead to kidney damage and certain cancers, posing a significant risk to infants and causing conditions like methemoglobinemia.
• The main source of nitrates in water is agricultural run-off entering the local water table.

HOW TO DETERMINE NITRATE PRESENCE IN WATER:

1. Use test kits available online or at home improvement stores to detect nitrates through a color-changing chemical solution.
2. Submit your water for testing in a laboratory, either through municipal health authorities or private labs.
3. Conduct visual inspections for reddish or brownish water or a metallic taste, indicating potential nitrate contamination.

NOTE: We do not provide testing services. It's essential to regularly test your water for safety, especially concerning nitrate exposure's serious health effects, particularly for young children and pregnant women.

If concerned about water quality, take prompt action to address the situation.

TYPICAL PHYSICAL-CHEMICAL CHARACTERISTICS:

* Weight of resin, as supplied, occupying 1 m in a unit after backwashing and draining.

This anion exchange resin is designed for versatile applications, including use in de-ionizing water filtration systems, chemical processing, and scientific settings. Its applications span the production of ultra-pure water, separation of organic substances, the refinement of antibiotic medicines, as well as the separation and extraction of biochemical products.

TANNIN REMOVAL
Experience the benefits of our specially designed water treatment medium that uses anionic resins to remove tannins and other negatively charged ions from your water, providing you with a pure and refreshing drink.

Tannin molecules tend to form anions in water above pH 6 and can be treated with anion exchange resins. Tannins below pH 5 are better treated with activated charcoal.

Using a softener beforehand removes hardness and metals (like iron) that might otherwise foul the anion resin, reducing its ability to remove tannins.

Tannin removal is dependent on the vegetation in a given area and thus the amount and type of resin necessary can vary. If your well water has a slight yellow or brown tint, the addition of one pound per inch in diameter of your media tank will normally make the water clear. If your water is darker, like Ice Tea, you may need as much as two pounds per inch in diameter of your media tank. There are various methods and each one can vary in result; this is why monitoring your water's results is an important factor in determining the desired results you want to achieve.

The "color" or "tannins" are tested by running the water at the well for a minute or two, then taking a sample in a cup or bucket and observing the color IMMEDIATELY before the iron reacts with the air (oxygen).

You only need the extra Tannin removal resin in with your regular softening resins if you have color when the water is first drawn.

CLEANING METHOD
When a tannin color passes through a working unit, an effort should be made to clean the resin. Soda ash (Na₂CO₃) can be added to the brine to aid in cleaning the anion resin. Typically, 0.5 to 1 pound of soda ash is added to the brine well. A second regeneration should follow after treating the resin with soda ash to fully convert the resin to the chloride form.

If the soda ash method fails to clean the resin, a chlorine treatment can be used as a last resort. This method is not recommended because it is extremely harsh on the resin. Fill the brine well with four to eight ounces of household bleach and set the system to regenerate. If a chlorine odor is detected in the drain line, shut down the system for one to two hours. After the system has soaked, complete the rest of the regeneration cycle. To eliminate any remaining chlorine, a second regeneration should be performed. Note that ion exchange resin is not chlorine resistant. If this treatment proves unsuccessful, replacement must be considered.

Before attempting any cleaning procedure, regenerate the bed with salt if the unit contains both cation and anion. Due to high pH or oxidation, any metals, such as iron, will precipitate on the cation resin.

SERVICE CYCLE
Tannin removal utilizing anion exchange resins combines both ion exchange and an absorption process. Tannins, having a slight negative charge, are exchanged for chloride in the resin. The regeneration of anion resin involves the use of salt (NaCl). Generally, the resin is brined at a rate of approximately 10 pounds of salt per cubic foot. Regular regeneration is crucial, with a recommended frequency of every two to three days. Notably, the anion resin is less dense than cation resin.

Backwashing of an anion resin should be conducted at a different flow rate compared to a cation-softening resin. A flow rate of about two gpm/sf is recommended for anion backwashing. Frequent regenerations are effective in reducing organic fouling.

Tannin resin is a residual by-product of anion resin, and the amine concentration is typically low, with an odor threshold around 40 parts per billion. Mixing ammonia and chlorine can create an environment that breaks down the resin, elevating the pH due to ammonia. If the Total Dissolved Solids (TDS) levels in the influent water exceed 800 ppm, a salty taste may be detected. The use of Reverse Osmosis (RO) is necessary to reduce TDS and eliminate the salty taste.

OTHER METHODS OF REMOVING TANNINS
Chlorine and other oxidizing agents prove effective in breaking down organic compounds like tannins. Conducting a simple jar test can determine the concentration and required time for oxidizing tannins. Post the retention tank, an activated carbon unit can eliminate chlorine and potentially adsorb other organic compounds in the water. Some types of activated carbon may independently reduce tannins to acceptable levels; for the appropriate carbon type, consult your carbon manufacturer. It's important to note that the reaction between chlorine and tannins may generate carcinogenic trihalomethanes (THMs).

Another successful method for tannin removal is reverse osmosis. However, tannins have a tendency to foul the system's membrane in this process. Installing a whole-house reverse osmosis system for comprehensive water treatment can be quite costly. For more information, consult your local water expert.

SAFETY
Caution should be exercised when handling the corrosive acid and alkali solutions used for regeneration to prevent contact with eyes and skin. Goggles and gloves are recommended throughout the entire process. When utilizing oxidizing agents, follow necessary safety precautions to prevent accidents and damage to the resin.

STORAGE
Ion exchange resins should be stored in a cool, shaded place, maintaining a moist environment. The recommended temperature range is between 20 and 40 degrees Celsius. Regularly inspect the resin, add clean demineralized water if needed, and ensure it remains completely moist. Never allow the resin to dry out. Always store the resin drum in the shade.

MAIN PURPOSE
Primarily used for water purification, wastewater treatment, biological products, and the hydrometallurgy of tungsten and molybdenum extraction.

OTHER USES
Additional applications include water softening, desalination of water preparation, preparation of pure water, and high water. Also employed in amino acid extraction and purification, extraction and purification of antibiotics, extraction and removal of heavy metal ions, separation and purification of rare earth elements, and organic synthesis reactions such as hydrolysis and acid esterification catalyst.

SPECIFICATIONS

• Size: 4.5" x 19 7/8", designed to fit Big Blue filter housings
• Resin Content: Contains 5.5-6.5 lbs of resin, depending on the media
• Operating Temperature Range: 40°F-125°F
• Operating Pressure Range: 40-80 PSI
• Minimum Operating Pressure: Maintain 60 PSI to avoid a drop in home water pressure

All filters are individually wrapped; store the product in a closed bag and keep it moist to prevent dryness. Avoid direct sunlight, and store the product at room temperature (40 to 75 Fahrenheit).

Caution: To prevent rapid buildups in the pre-woven filter and ensure the Nitrate filter's longer lifespan without quick clogging and a subsequent drop in pressure throughout your entire home, always install this filter after the sediment filter.

Additionally, it is recommended to follow this filter with either a CTO or GAC carbon filter to effectively combat any unpleasant odors that may arise during the Tannin-to-Chloride exchange. Without a carbon filter after the Tannin filter, there is no effective way to address the issue of foul odors.

20" Big Blue Anion Resin Tannin Reduction Filter

Introducing the 20" Big Blue Anion Resin Filter designed for effective Tannin Reduction. This filter utilizes food-grade strong base anion resin to efficiently decrease and eliminate tannins and nitrates from your incoming water. If you're dealing with well water or experiencing a persistent brownish discoloration that standard sediment or Iron/Manganese filters can't address, the anion filter may be the ideal solution for your needs.

WHAT IS TANNIN?

• Tannins are large organic compounds found in plants, particularly in the bark, leaves, and fruits of certain trees, and to a lesser extent in animals.
• These astringent and bitter-tasting polyphenols bind and precipitate proteins and vary in structure depending on the local vegetation.
• In water treatment, tannins can cause discoloration, and a bitter taste, and reduce R.O. system effectiveness, impacting water quality.
• It is crucial to remove tannins from water used in R.O. systems with pH 6, and anion exchange resins can be effective for this purpose.

WHAT IS NITRATE?

• Nitrates are chemical salts naturally found in mineral deposits and commonly used in fertilizers.
• Long-term nitrate exposure can lead to kidney damage and certain cancers, posing a significant risk to infants and causing conditions like methemoglobinemia.
• The main source of nitrates in water is agricultural run-off entering the local water table.

HOW TO DETERMINE NITRATE PRESENCE IN WATER:

1. Use test kits available online or at home improvement stores to detect nitrates through a color-changing chemical solution.
2. Submit your water for testing in a laboratory, either through municipal health authorities or private labs.
3. Conduct visual inspections for reddish or brownish water or a metallic taste, indicating potential nitrate contamination.

NOTE: We do not provide testing services. It's essential to regularly test your water for safety, especially concerning nitrate exposure's serious health effects, particularly for young children and pregnant women.

If concerned about water quality, take prompt action to address the situation.

TYPICAL PHYSICAL-CHEMICAL CHARACTERISTICS:

* Weight of resin, as supplied, occupying 1 m in a unit after backwashing and draining.

This anion exchange resin is designed for versatile applications, including use in de-ionizing water filtration systems, chemical processing, and scientific settings. Its applications span the production of ultra-pure water, separation of organic substances, the refinement of antibiotic medicines, as well as the separation and extraction of biochemical products.

TANNIN REMOVAL
Experience the benefits of our specially designed water treatment medium that uses anionic resins to remove tannins and other negatively charged ions from your water, providing you with a pure and refreshing drink.

Tannin molecules tend to form anions in water above pH 6 and can be treated with anion exchange resins. Tannins below pH 5 are better treated with activated charcoal.

Using a softener beforehand removes hardness and metals (like iron) that might otherwise foul the anion resin, reducing its ability to remove tannins.

Tannin removal is dependent on the vegetation in a given area and thus the amount and type of resin necessary can vary. If your well water has a slight yellow or brown tint, the addition of one pound per inch in diameter of your media tank will normally make the water clear. If your water is darker, like Ice Tea, you may need as much as two pounds per inch in diameter of your media tank. There are various methods and each one can vary in result; this is why monitoring your water's results is an important factor in determining the desired results you want to achieve.

The "color" or "tannins" are tested by running the water at the well for a minute or two, then taking a sample in a cup or bucket and observing the color IMMEDIATELY before the iron reacts with the air (oxygen).

You only need the extra Tannin removal resin in with your regular softening resins if you have color when the water is first drawn.

CLEANING METHOD
When a tannin color passes through a working unit, an effort should be made to clean the resin. Soda ash (Na₂CO₃) can be added to the brine to aid in cleaning the anion resin. Typically, 0.5 to 1 pound of soda ash is added to the brine well. A second regeneration should follow after treating the resin with soda ash to fully convert the resin to the chloride form.

If the soda ash method fails to clean the resin, a chlorine treatment can be used as a last resort. This method is not recommended because it is extremely harsh on the resin. Fill the brine well with four to eight ounces of household bleach and set the system to regenerate. If a chlorine odor is detected in the drain line, shut down the system for one to two hours. After the system has soaked, complete the rest of the regeneration cycle. To eliminate any remaining chlorine, a second regeneration should be performed. Note that ion exchange resin is not chlorine resistant. If this treatment proves unsuccessful, replacement must be considered.

Before attempting any cleaning procedure, regenerate the bed with salt if the unit contains both cation and anion. Due to high pH or oxidation, any metals, such as iron, will precipitate on the cation resin.

SERVICE CYCLE
Tannin removal utilizing anion exchange resins combines both ion exchange and an absorption process. Tannins, having a slight negative charge, are exchanged for chloride in the resin. The regeneration of anion resin involves the use of salt (NaCl). Generally, the resin is brined at a rate of approximately 10 pounds of salt per cubic foot. Regular regeneration is crucial, with a recommended frequency of every two to three days. Notably, the anion resin is less dense than cation resin.

Backwashing of an anion resin should be conducted at a different flow rate compared to a cation-softening resin. A flow rate of about two gpm/sf is recommended for anion backwashing. Frequent regenerations are effective in reducing organic fouling.

Tannin resin is a residual by-product of anion resin, and the amine concentration is typically low, with an odor threshold around 40 parts per billion. Mixing ammonia and chlorine can create an environment that breaks down the resin, elevating the pH due to ammonia. If the Total Dissolved Solids (TDS) levels in the influent water exceed 800 ppm, a salty taste may be detected. The use of Reverse Osmosis (RO) is necessary to reduce TDS and eliminate the salty taste.

OTHER METHODS OF REMOVING TANNINS
Chlorine and other oxidizing agents prove effective in breaking down organic compounds like tannins. Conducting a simple jar test can determine the concentration and required time for oxidizing tannins. Post the retention tank, an activated carbon unit can eliminate chlorine and potentially adsorb other organic compounds in the water. Some types of activated carbon may independently reduce tannins to acceptable levels; for the appropriate carbon type, consult your carbon manufacturer. It's important to note that the reaction between chlorine and tannins may generate carcinogenic trihalomethanes (THMs).

Another successful method for tannin removal is reverse osmosis. However, tannins have a tendency to foul the system's membrane in this process. Installing a whole-house reverse osmosis system for comprehensive water treatment can be quite costly. For more information, consult your local water expert.

SAFETY
Caution should be exercised when handling the corrosive acid and alkali solutions used for regeneration to prevent contact with eyes and skin. Goggles and gloves are recommended throughout the entire process. When utilizing oxidizing agents, follow necessary safety precautions to prevent accidents and damage to the resin.

STORAGE
Ion exchange resins should be stored in a cool, shaded place, maintaining a moist environment. The recommended temperature range is between 20 and 40 degrees Celsius. Regularly inspect the resin, add clean demineralized water if needed, and ensure it remains completely moist. Never allow the resin to dry out. Always store the resin drum in the shade.

MAIN PURPOSE
Primarily used for water purification, wastewater treatment, biological products, and the hydrometallurgy of tungsten and molybdenum extraction.

OTHER USES
Additional applications include water softening, desalination of water preparation, preparation of pure water, and high water. Also employed in amino acid extraction and purification, extraction and purification of antibiotics, extraction and removal of heavy metal ions, separation and purification of rare earth elements, and organic synthesis reactions such as hydrolysis and acid esterification catalyst.

SPECIFICATIONS

• Size: 4.5" x 19 7/8", designed to fit Big Blue filter housings
• Resin Content: Contains 5.5-6.5 lbs of resin, depending on the media
• Operating Temperature Range: 40°F-125°F
• Operating Pressure Range: 40-80 PSI
• Minimum Operating Pressure: Maintain 60 PSI to avoid a drop in home water pressure

All filters are individually wrapped; store the product in a closed bag and keep it moist to prevent dryness. Avoid direct sunlight, and store the product at room temperature (40 to 75 Fahrenheit).

Caution: To prevent rapid buildups in the pre-woven filter and ensure the Nitrate filter's longer lifespan without quick clogging and a subsequent drop in pressure throughout your entire home, always install this filter after the sediment filter.

Additionally, it is recommended to follow this filter with either a CTO or GAC carbon filter to effectively combat any unpleasant odors that may arise during the Tannin-to-Chloride exchange. Without a carbon filter after the Tannin filter, there is no effective way to address the issue of foul odors.

Anion Resin for Tannin Reduction - 5 lbs Bag

A High Capacity Anion Exchange Resin for Domestic Applications

NOTE: Five pounds of resin is enough to refill a 20" x 4.5" refillable filter (for standard 20" housing) about 1 time.

Utilize our potent strong base anion resin to effectively diminish and eliminate tannins from your incoming water supply. Available in bulk bags for convenient refilling of filter cartridges (sold separately). If you're dealing with well water or experiencing persistent brown discoloration that standard sediment or Iron/Manganese filters can't address, consider an anion filter as a potential solution.

Tannins, known for their astringent and bitter taste, are plant polyphenols that bind and precipitate proteins. In the context of water treatment, the term refers to the brown discoloration caused by decaying organic matter, often present in well waters due to the formation of tannins from humic acid. This acid, a complex mixture resulting from the biodegradation of organic matter, contains carboxyl and phenolate groups.

Primary Uses:

• Water purification
• Wastewater treatment
• Biological product processing
• Hydrometallurgy of tungsten
• Molybdenum extraction

Other Applications:

• Water softening
• Desalination of water preparation
• Preparation of pure water and high water
• Amino acid extraction and purification
• Extraction and purification of antibiotics
• Extraction and removal of heavy metal ions
• Separation and purification of rare earth elements
• Organic synthesis reactions, acting as a hydrolysis and acid esterification catalyst.

Tannin Removal

• Addressing tannin removal has posed a challenge for some dealers, with standard strong base macroporous anion resins, crafted from styrene and divinylbenzene, traditionally employed until several years ago. Although effective in certain regions, this resin type encountered limitations in others. Over the past five to ten years, the residential water market has witnessed the introduction of more successful resins, making the tannin removal application more appealing to water treatment dealers.
• Softening the water before the tannin removal unit is often recommended. This step ensures the elimination of hardness and metals like iron, which could potentially compromise the performance of the anion resin. Tannins, however, can pass through softening (cation) resin without adverse effects. When hardness levels exceed 10 grains entering the tannin removal unit, there's a risk of precipitating calcium carbonate, forming a white floc that may impede system flow and obstruct exchange sites on the resin. Additionally, metals like iron can foul the anion resin, diminishing its ability to remove tannins. Methods for cleaning these foulants will be discussed later.
• Tannins, large molecular-weight organic compounds resulting from plant and animal decomposition, primarily exist in surface waters or shallow wells. Two main categories of tannins are Humic acid and Fulvic acid, each exhibiting varying structures depending on the vegetation in a given area. Tannins can impart a yellow to dark tea color to water, affecting taste and odor. While not directly regulated, a secondary drinking water standard of 15 alpha units for color exists, although it is not federally enforced. Although not posing health concerns, tannins are aesthetically displeasing.
• Dealing with tannins in water can be challenging, with treatment methods varying in effectiveness based on location and vegetation. While styrene-based macroporous anion resin has traditionally been used for tannin removal, acrylic-based resins have recently emerged, providing excellent results in most cases. These resins can be manufactured as gels or with macroporosity, and low crosslinked/high water retention styrene-based resins have also proven successful in some applications.

If your well water exhibits a slight yellow or brown tint, adding one pound per inch in diameter to your media tank typically restores clarity to the water. For darker water resembling iced tea, you may require up to two pounds per inch in diameter of your media tank.

Although there's mention of using a separate tank solely for tannin removal, our approach involves directly introducing these beads into the existing tank, on top of the regular ones in the water softener, without removing any beads.

To assess the "color" or "tannins," run the water at the well for a brief period, then promptly take a sample in a white cup, bucket, or clear glass. Observe the color immediately before the iron has a chance to react with the air (oxygen). Only if color is present when water is initially drawn would the additional tannin removal resin be deemed necessary alongside your regular softening resins.

Application - Organics; Tannin Removal and Demineralization - Demonstrates excellent resistance to fouling.

Here is some general information on estimating the approximate level of tannins in your water.

Service Cycle Overview:

• The process of tannin removal using anion exchange resins involves a dual mechanism of ion exchange and absorption. Tannins, possessing a slightly negative charge, are exchanged for chloride ions on the resin. Additionally, it is believed that the anion resin can absorb organic compounds. Regeneration of the anion resin is achieved using salt, typically brined at around 10 lbs per cubic foot of salt (NaCl). Regular regeneration is crucial to maintaining resin efficacy.
• Once tannins are exchanged or absorbed onto the resin, they tend to migrate into the inner matrix of the resin bead. Timely regeneration, ideally every two to three days, is essential. Frequent regenerations decrease the likelihood of organic fouling, while extended intervals promote fouling, regardless of whether the anion resin is acrylic or styrene-based.
• The incorporation of tannin resin with softening resin is a common practice, optimizing equipment space and reducing system costs. However, during regeneration, salt may displace calcium from the cation resin and potentially alkalinity from the anion/tannin resin, leading to calcium carbonate precipitation. Indicators of precipitation include a white precipitate in the resin bed, a coating on the drain line, a pressure drop through the system, or a milky-white substance in the backwash water. Cleaning methods will be discussed later.
• Anion resin, with lower density compared to cation resin, requires a distinct backwash flow rate. While the backwash flow rate for cation-softening resin is approximately five gpm/square foot (sf) of area, the anion should be backwashed at around two gpm/sf. In dual bed systems combining softening and tannin removal resins, backwash adjustments or the use of an upper screen or basket in the valve prevent resin loss.
• Tannin resin is often associated with a fishy odor, attributed to the release of an amine by-product from the anion resin. Although the amine concentrations are generally low, the odor threshold is around 40 parts per billion, causing aesthetic displeasure. The fishy odor is more prevalent when water is chlorinated and has a high pH (>8), often occurring with the use of chloramines as a disinfectant. It is advisable to remove any oxidant (chlorine, chloramine, or peroxide) before the anion unit.
• As water passes through a chloride-form anion resin, alkalinity is removed, leading to a decrease in pH. The anion resin has a limited capacity for alkalinity, causing a brief pH decrease during the service cycle. The treated water's chloride content increases, and it is essential to check local water treatment regulations for any chloride limits. Chlorides have a secondary drinking water standard of 250 ppm. If influent water TDS levels exceed 800 ppm, a salty taste may be detected in the treated water, necessitating the use of reverse osmosis (RO) to reduce TDS and eliminate the salty taste.

Methods of Cleaning:

• To address calcium carbonate precipitation, a weak acid such as citric or phosphoric acid proves effective. Compatibility with the unit and associated plumbing is essential when selecting a cleaning agent, and this method is generally suitable for treating various types of metal fouling.
• When tannin color passes through a previously functioning unit, an attempt to clean the resin is warranted. For this, soda ash (Na2CO3) can be introduced into the brine to aid in cleaning the anion resin. Typically, 0.5 to 1 pound of soda ash is added to the brine well. The soda ash elevates the pH of the brine, causing the resin to swell further, enlarging the pores for enhanced elution of tannins. Additionally, tannins are more soluble at higher pH levels, creating an environment conducive to stripping them from the resin. Note that this cleaning process may result in the fishy odor. After treating the resin with soda ash, a second regeneration should be conducted to completely convert the resin to the chloride form.
• If soda ash proves ineffective in cleaning the resin, chlorine treatment can be employed as a last resort. Introduce approximately four to eight ounces of standard household bleach into the brine well and initiate the regeneration process. Once a chlorine odor is discernible in the drain line, pause the system for one to two hours, and resume the remainder of the regeneration cycle after the soak. A second regeneration is necessary to eliminate any residual chlorine. It's crucial to recognize that this cleaning procedure is harsh on the resin and should be considered a final option. Oxidants like chlorine can break down ion exchange resin, and although there is no resin on the market that is entirely chlorine-resistant, some are more chlorine-tolerant. The tannin resins in today's water treatment market are relatively chlorine-intolerant. If this treatment proves unsuccessful, replacement should be contemplated.
• If the unit houses both cation and anion, it is advisable to regenerate the bed with salt before attempting any cleaning procedure. Metals, such as iron, may precipitate on the cation resin due to high pH or oxidation.

Alternative Approaches to Tannin Removal:

• Oxidizing agents, such as chlorine, prove effective in breaking down organic compounds like tannins. A simple jar test can reveal the concentration and retention time needed to oxidize tannins. Following the retention tank, an activated carbon unit can eliminate chlorine and potentially adsorb other organic compounds in the water. Certain types of activated carbon alone may also reduce tannin levels to acceptable thresholds. It is crucial to consult with your carbon manufacturer to identify the most suitable product. It's worth noting that the reaction between chlorine and tannins may generate trihalomethanes (THMs), recognized carcinogens.
• Reverse osmosis represents another viable method for tannin removal. Given that tannins are high molecular weight organics, reverse osmosis should effectively reject them. However, tannins may pose a challenge by fouling the membrane in the system. Additionally, installing a whole-house reverse osmosis system to treat all water can be prohibitively expensive. For detailed information, it is recommended to consult with your local water expert.

Conclusion:

• Historically, tannin removal predominantly relied on carbon- and styrene-based ion exchange resins. However, recent advancements in water treatment have introduced acrylic-based and high water retention/low crosslinked styrene-based anion exchange resins to the residential market, demonstrating superior performance in tannin removal compared to traditional ion exchange resins. While no resin achieves 100 percent effectiveness, these newer resins have significantly enhanced success rates. If you haven't attempted tannin treatment recently, it might be worth exploring again. For any new water treatment application or product, conduct pilot testing with several systems in the field. Once the pilot study validates the effectiveness in a specific area, pursue the business.

Storage:

• Proper care is essential for ion exchange resins throughout their storage. Prevent the resins from drying out by regularly inspecting their condition when stored in plastic bags. If the resin is not moist, add sufficient clean demineralized water to maintain a consistently moist state. Store the resin drum in a shaded area, and the recommended storage temperature falls between 20°C and 40°C.

Safety:

• Exercise caution with acid and alkali solutions used for regeneration, as they are corrosive and should be handled to prevent eye and skin contact. When utilizing oxidizing agents, adhere to necessary safety precautions to prevent accidents and potential damage to the resin.

20" Big Blue Anion Resin Tannin Reduction Filter

Introducing the 20" Big Blue Anion Resin Filter designed for effective Tannin Reduction. This filter utilizes food-grade strong base anion resin to efficiently decrease and eliminate tannins and nitrates from your incoming water. If you're dealing with well water or experiencing a persistent brownish discoloration that standard sediment or Iron/Manganese filters can't address, the anion filter may be the ideal solution for your needs.

WHAT IS TANNIN?

• Tannins are large organic compounds found in plants, particularly in the bark, leaves, and fruits of certain trees, and to a lesser extent in animals.
• These astringent and bitter-tasting polyphenols bind and precipitate proteins and vary in structure depending on the local vegetation.
• In water treatment, tannins can cause discoloration, and a bitter taste, and reduce R.O. system effectiveness, impacting water quality.
• It is crucial to remove tannins from water used in R.O. systems with pH 6, and anion exchange resins can be effective for this purpose.

WHAT IS NITRATE?

• Nitrates are chemical salts naturally found in mineral deposits and commonly used in fertilizers.
• Long-term nitrate exposure can lead to kidney damage and certain cancers, posing a significant risk to infants and causing conditions like methemoglobinemia.
• The main source of nitrates in water is agricultural run-off entering the local water table.

HOW TO DETERMINE NITRATE PRESENCE IN WATER:

1. Use test kits available online or at home improvement stores to detect nitrates through a color-changing chemical solution.
2. Submit your water for testing in a laboratory, either through municipal health authorities or private labs.
3. Conduct visual inspections for reddish or brownish water or a metallic taste, indicating potential nitrate contamination.

NOTE: We do not provide testing services. It's essential to regularly test your water for safety, especially concerning nitrate exposure's serious health effects, particularly for young children and pregnant women.

If concerned about water quality, take prompt action to address the situation.

TYPICAL PHYSICAL-CHEMICAL CHARACTERISTICS:

* Weight of resin, as supplied, occupying 1 m in a unit after backwashing and draining.

This anion exchange resin is designed for versatile applications, including use in de-ionizing water filtration systems, chemical processing, and scientific settings. Its applications span the production of ultra-pure water, separation of organic substances, the refinement of antibiotic medicines, as well as the separation and extraction of biochemical products.

TANNIN REMOVAL
Experience the benefits of our specially designed water treatment medium that uses anionic resins to remove tannins and other negatively charged ions from your water, providing you with a pure and refreshing drink.

Tannin molecules tend to form anions in water above pH 6 and can be treated with anion exchange resins. Tannins below pH 5 are better treated with activated charcoal.

Using a softener beforehand removes hardness and metals (like iron) that might otherwise foul the anion resin, reducing its ability to remove tannins.

Tannin removal is dependent on the vegetation in a given area and thus the amount and type of resin necessary can vary. If your well water has a slight yellow or brown tint, the addition of one pound per inch in diameter of your media tank will normally make the water clear. If your water is darker, like Ice Tea, you may need as much as two pounds per inch in diameter of your media tank. There are various methods and each one can vary in result; this is why monitoring your water's results is an important factor in determining the desired results you want to achieve.

The "color" or "tannins" are tested by running the water at the well for a minute or two, then taking a sample in a cup or bucket and observing the color IMMEDIATELY before the iron reacts with the air (oxygen).

You only need the extra Tannin removal resin in with your regular softening resins if you have color when the water is first drawn.

CLEANING METHOD
When a tannin color passes through a working unit, an effort should be made to clean the resin. Soda ash (Na₂CO₃) can be added to the brine to aid in cleaning the anion resin. Typically, 0.5 to 1 pound of soda ash is added to the brine well. A second regeneration should follow after treating the resin with soda ash to fully convert the resin to the chloride form.

If the soda ash method fails to clean the resin, a chlorine treatment can be used as a last resort. This method is not recommended because it is extremely harsh on the resin. Fill the brine well with four to eight ounces of household bleach and set the system to regenerate. If a chlorine odor is detected in the drain line, shut down the system for one to two hours. After the system has soaked, complete the rest of the regeneration cycle. To eliminate any remaining chlorine, a second regeneration should be performed. Note that ion exchange resin is not chlorine resistant. If this treatment proves unsuccessful, replacement must be considered.

Before attempting any cleaning procedure, regenerate the bed with salt if the unit contains both cation and anion. Due to high pH or oxidation, any metals, such as iron, will precipitate on the cation resin.

SERVICE CYCLE
Tannin removal utilizing anion exchange resins combines both ion exchange and an absorption process. Tannins, having a slight negative charge, are exchanged for chloride in the resin. The regeneration of anion resin involves the use of salt (NaCl). Generally, the resin is brined at a rate of approximately 10 pounds of salt per cubic foot. Regular regeneration is crucial, with a recommended frequency of every two to three days. Notably, the anion resin is less dense than cation resin.

Backwashing of an anion resin should be conducted at a different flow rate compared to a cation-softening resin. A flow rate of about two gpm/sf is recommended for anion backwashing. Frequent regenerations are effective in reducing organic fouling.

Tannin resin is a residual by-product of anion resin, and the amine concentration is typically low, with an odor threshold around 40 parts per billion. Mixing ammonia and chlorine can create an environment that breaks down the resin, elevating the pH due to ammonia. If the Total Dissolved Solids (TDS) levels in the influent water exceed 800 ppm, a salty taste may be detected. The use of Reverse Osmosis (RO) is necessary to reduce TDS and eliminate the salty taste.

OTHER METHODS OF REMOVING TANNINS
Chlorine and other oxidizing agents prove effective in breaking down organic compounds like tannins. Conducting a simple jar test can determine the concentration and required time for oxidizing tannins. Post the retention tank, an activated carbon unit can eliminate chlorine and potentially adsorb other organic compounds in the water. Some types of activated carbon may independently reduce tannins to acceptable levels; for the appropriate carbon type, consult your carbon manufacturer. It's important to note that the reaction between chlorine and tannins may generate carcinogenic trihalomethanes (THMs).

Another successful method for tannin removal is reverse osmosis. However, tannins have a tendency to foul the system's membrane in this process. Installing a whole-house reverse osmosis system for comprehensive water treatment can be quite costly. For more information, consult your local water expert.

SAFETY
Caution should be exercised when handling the corrosive acid and alkali solutions used for regeneration to prevent contact with eyes and skin. Goggles and gloves are recommended throughout the entire process. When utilizing oxidizing agents, follow necessary safety precautions to prevent accidents and damage to the resin.

STORAGE
Ion exchange resins should be stored in a cool, shaded place, maintaining a moist environment. The recommended temperature range is between 20 and 40 degrees Celsius. Regularly inspect the resin, add clean demineralized water if needed, and ensure it remains completely moist. Never allow the resin to dry out. Always store the resin drum in the shade.

MAIN PURPOSE
Primarily used for water purification, wastewater treatment, biological products, and the hydrometallurgy of tungsten and molybdenum extraction.

OTHER USES
Additional applications include water softening, desalination of water preparation, preparation of pure water, and high water. Also employed in amino acid extraction and purification, extraction and purification of antibiotics, extraction and removal of heavy metal ions, separation and purification of rare earth elements, and organic synthesis reactions such as hydrolysis and acid esterification catalyst.

SPECIFICATIONS

• Size: 4.5" x 19 7/8", designed to fit Big Blue filter housings
• Resin Content: Contains 5.5-6.5 lbs of resin, depending on the media
• Operating Temperature Range: 40°F-125°F
• Operating Pressure Range: 40-80 PSI
• Minimum Operating Pressure: Maintain 60 PSI to avoid a drop in home water pressure

All filters are individually wrapped; store the product in a closed bag and keep it moist to prevent dryness. Avoid direct sunlight, and store the product at room temperature (40 to 75 Fahrenheit).

Caution: To prevent rapid buildups in the pre-woven filter and ensure the Nitrate filter's longer lifespan without quick clogging and a subsequent drop in pressure throughout your entire home, always install this filter after the sediment filter.

Additionally, it is recommended to follow this filter with either a CTO or GAC carbon filter to effectively combat any unpleasant odors that may arise during the Tannin-to-Chloride exchange. Without a carbon filter after the Tannin filter, there is no effective way to address the issue of foul odors.

20" Big Blue Anion Resin Tannin Reduction Filter

Introducing the 20" Big Blue Anion Resin Filter designed for effective Tannin Reduction. This filter utilizes food-grade strong base anion resin to efficiently decrease and eliminate tannins and nitrates from your incoming water. If you're dealing with well water or experiencing a persistent brownish discoloration that standard sediment or Iron/Manganese filters can't address, the anion filter may be the ideal solution for your needs.

WHAT IS TANNIN?

• Tannins are large organic compounds found in plants, particularly in the bark, leaves, and fruits of certain trees, and to a lesser extent in animals.
• These astringent and bitter-tasting polyphenols bind and precipitate proteins and vary in structure depending on the local vegetation.
• In water treatment, tannins can cause discoloration, and a bitter taste, and reduce R.O. system effectiveness, impacting water quality.
• It is crucial to remove tannins from water used in R.O. systems with pH 6, and anion exchange resins can be effective for this purpose.

WHAT IS NITRATE?

• Nitrates are chemical salts naturally found in mineral deposits and commonly used in fertilizers.
• Long-term nitrate exposure can lead to kidney damage and certain cancers, posing a significant risk to infants and causing conditions like methemoglobinemia.
• The main source of nitrates in water is agricultural run-off entering the local water table.

HOW TO DETERMINE NITRATE PRESENCE IN WATER:

1. Use test kits available online or at home improvement stores to detect nitrates through a color-changing chemical solution.
2. Submit your water for testing in a laboratory, either through municipal health authorities or private labs.
3. Conduct visual inspections for reddish or brownish water or a metallic taste, indicating potential nitrate contamination.

NOTE: We do not provide testing services. It's essential to regularly test your water for safety, especially concerning nitrate exposure's serious health effects, particularly for young children and pregnant women.

If concerned about water quality, take prompt action to address the situation.

TYPICAL PHYSICAL-CHEMICAL CHARACTERISTICS:

* Weight of resin, as supplied, occupying 1 m in a unit after backwashing and draining.

This anion exchange resin is designed for versatile applications, including use in de-ionizing water filtration systems, chemical processing, and scientific settings. Its applications span the production of ultra-pure water, separation of organic substances, the refinement of antibiotic medicines, as well as the separation and extraction of biochemical products.

TANNIN REMOVAL
Experience the benefits of our specially designed water treatment medium that uses anionic resins to remove tannins and other negatively charged ions from your water, providing you with a pure and refreshing drink.

Tannin molecules tend to form anions in water above pH 6 and can be treated with anion exchange resins. Tannins below pH 5 are better treated with activated charcoal.

Using a softener beforehand removes hardness and metals (like iron) that might otherwise foul the anion resin, reducing its ability to remove tannins.

Tannin removal is dependent on the vegetation in a given area and thus the amount and type of resin necessary can vary. If your well water has a slight yellow or brown tint, the addition of one pound per inch in diameter of your media tank will normally make the water clear. If your water is darker, like Ice Tea, you may need as much as two pounds per inch in diameter of your media tank. There are various methods and each one can vary in result; this is why monitoring your water's results is an important factor in determining the desired results you want to achieve.

The "color" or "tannins" are tested by running the water at the well for a minute or two, then taking a sample in a cup or bucket and observing the color IMMEDIATELY before the iron reacts with the air (oxygen).

You only need the extra Tannin removal resin in with your regular softening resins if you have color when the water is first drawn.

CLEANING METHOD
When a tannin color passes through a working unit, an effort should be made to clean the resin. Soda ash (Na₂CO₃) can be added to the brine to aid in cleaning the anion resin. Typically, 0.5 to 1 pound of soda ash is added to the brine well. A second regeneration should follow after treating the resin with soda ash to fully convert the resin to the chloride form.

If the soda ash method fails to clean the resin, a chlorine treatment can be used as a last resort. This method is not recommended because it is extremely harsh on the resin. Fill the brine well with four to eight ounces of household bleach and set the system to regenerate. If a chlorine odor is detected in the drain line, shut down the system for one to two hours. After the system has soaked, complete the rest of the regeneration cycle. To eliminate any remaining chlorine, a second regeneration should be performed. Note that ion exchange resin is not chlorine resistant. If this treatment proves unsuccessful, replacement must be considered.

Before attempting any cleaning procedure, regenerate the bed with salt if the unit contains both cation and anion. Due to high pH or oxidation, any metals, such as iron, will precipitate on the cation resin.

SERVICE CYCLE
Tannin removal utilizing anion exchange resins combines both ion exchange and an absorption process. Tannins, having a slight negative charge, are exchanged for chloride in the resin. The regeneration of anion resin involves the use of salt (NaCl). Generally, the resin is brined at a rate of approximately 10 pounds of salt per cubic foot. Regular regeneration is crucial, with a recommended frequency of every two to three days. Notably, the anion resin is less dense than cation resin.

Backwashing of an anion resin should be conducted at a different flow rate compared to a cation-softening resin. A flow rate of about two gpm/sf is recommended for anion backwashing. Frequent regenerations are effective in reducing organic fouling.

Tannin resin is a residual by-product of anion resin, and the amine concentration is typically low, with an odor threshold around 40 parts per billion. Mixing ammonia and chlorine can create an environment that breaks down the resin, elevating the pH due to ammonia. If the Total Dissolved Solids (TDS) levels in the influent water exceed 800 ppm, a salty taste may be detected. The use of Reverse Osmosis (RO) is necessary to reduce TDS and eliminate the salty taste.

OTHER METHODS OF REMOVING TANNINS
Chlorine and other oxidizing agents prove effective in breaking down organic compounds like tannins. Conducting a simple jar test can determine the concentration and required time for oxidizing tannins. Post the retention tank, an activated carbon unit can eliminate chlorine and potentially adsorb other organic compounds in the water. Some types of activated carbon may independently reduce tannins to acceptable levels; for the appropriate carbon type, consult your carbon manufacturer. It's important to note that the reaction between chlorine and tannins may generate carcinogenic trihalomethanes (THMs).

Another successful method for tannin removal is reverse osmosis. However, tannins have a tendency to foul the system's membrane in this process. Installing a whole-house reverse osmosis system for comprehensive water treatment can be quite costly. For more information, consult your local water expert.

SAFETY
Caution should be exercised when handling the corrosive acid and alkali solutions used for regeneration to prevent contact with eyes and skin. Goggles and gloves are recommended throughout the entire process. When utilizing oxidizing agents, follow necessary safety precautions to prevent accidents and damage to the resin.

STORAGE
Ion exchange resins should be stored in a cool, shaded place, maintaining a moist environment. The recommended temperature range is between 20 and 40 degrees Celsius. Regularly inspect the resin, add clean demineralized water if needed, and ensure it remains completely moist. Never allow the resin to dry out. Always store the resin drum in the shade.

MAIN PURPOSE
Primarily used for water purification, wastewater treatment, biological products, and the hydrometallurgy of tungsten and molybdenum extraction.

OTHER USES
Additional applications include water softening, desalination of water preparation, preparation of pure water, and high water. Also employed in amino acid extraction and purification, extraction and purification of antibiotics, extraction and removal of heavy metal ions, separation and purification of rare earth elements, and organic synthesis reactions such as hydrolysis and acid esterification catalyst.

SPECIFICATIONS

• Size: 4.5" x 19 7/8", designed to fit Big Blue filter housings
• Resin Content: Contains 5.5-6.5 lbs of resin, depending on the media
• Operating Temperature Range: 40°F-125°F
• Operating Pressure Range: 40-80 PSI
• Minimum Operating Pressure: Maintain 60 PSI to avoid a drop in home water pressure

All filters are individually wrapped; store the product in a closed bag and keep it moist to prevent dryness. Avoid direct sunlight, and store the product at room temperature (40 to 75 Fahrenheit).

Caution: To prevent rapid buildups in the pre-woven filter and ensure the Nitrate filter's longer lifespan without quick clogging and a subsequent drop in pressure throughout your entire home, always install this filter after the sediment filter.

Additionally, it is recommended to follow this filter with either a CTO or GAC carbon filter to effectively combat any unpleasant odors that may arise during the Tannin-to-Chloride exchange. Without a carbon filter after the Tannin filter, there is no effective way to address the issue of foul odors.

20" Big Blue Anion Resin Tannin Reduction Filter

Introducing the 20" Big Blue Anion Resin Filter designed for effective Tannin Reduction. This filter utilizes food-grade strong base anion resin to efficiently decrease and eliminate tannins and nitrates from your incoming water. If you're dealing with well water or experiencing a persistent brownish discoloration that standard sediment or Iron/Manganese filters can't address, the anion filter may be the ideal solution for your needs.

WHAT IS TANNIN?

• Tannins are large organic compounds found in plants, particularly in the bark, leaves, and fruits of certain trees, and to a lesser extent in animals.
• These astringent and bitter-tasting polyphenols bind and precipitate proteins and vary in structure depending on the local vegetation.
• In water treatment, tannins can cause discoloration, and a bitter taste, and reduce R.O. system effectiveness, impacting water quality.
• It is crucial to remove tannins from water used in R.O. systems with pH 6, and anion exchange resins can be effective for this purpose.

WHAT IS NITRATE?

• Nitrates are chemical salts naturally found in mineral deposits and commonly used in fertilizers.
• Long-term nitrate exposure can lead to kidney damage and certain cancers, posing a significant risk to infants and causing conditions like methemoglobinemia.
• The main source of nitrates in water is agricultural run-off entering the local water table.

HOW TO DETERMINE NITRATE PRESENCE IN WATER:

1. Use test kits available online or at home improvement stores to detect nitrates through a color-changing chemical solution.
2. Submit your water for testing in a laboratory, either through municipal health authorities or private labs.
3. Conduct visual inspections for reddish or brownish water or a metallic taste, indicating potential nitrate contamination.

NOTE: We do not provide testing services. It's essential to regularly test your water for safety, especially concerning nitrate exposure's serious health effects, particularly for young children and pregnant women.

If concerned about water quality, take prompt action to address the situation.

TYPICAL PHYSICAL-CHEMICAL CHARACTERISTICS:

* Weight of resin, as supplied, occupying 1 m in a unit after backwashing and draining.

This anion exchange resin is designed for versatile applications, including use in de-ionizing water filtration systems, chemical processing, and scientific settings. Its applications span the production of ultra-pure water, separation of organic substances, the refinement of antibiotic medicines, as well as the separation and extraction of biochemical products.

TANNIN REMOVAL
Experience the benefits of our specially designed water treatment medium that uses anionic resins to remove tannins and other negatively charged ions from your water, providing you with a pure and refreshing drink.

Tannin molecules tend to form anions in water above pH 6 and can be treated with anion exchange resins. Tannins below pH 5 are better treated with activated charcoal.

Using a softener beforehand removes hardness and metals (like iron) that might otherwise foul the anion resin, reducing its ability to remove tannins.

Tannin removal is dependent on the vegetation in a given area and thus the amount and type of resin necessary can vary. If your well water has a slight yellow or brown tint, the addition of one pound per inch in diameter of your media tank will normally make the water clear. If your water is darker, like Ice Tea, you may need as much as two pounds per inch in diameter of your media tank. There are various methods and each one can vary in result; this is why monitoring your water's results is an important factor in determining the desired results you want to achieve.

The "color" or "tannins" are tested by running the water at the well for a minute or two, then taking a sample in a cup or bucket and observing the color IMMEDIATELY before the iron reacts with the air (oxygen).

You only need the extra Tannin removal resin in with your regular softening resins if you have color when the water is first drawn.

CLEANING METHOD
When a tannin color passes through a working unit, an effort should be made to clean the resin. Soda ash (Na₂CO₃) can be added to the brine to aid in cleaning the anion resin. Typically, 0.5 to 1 pound of soda ash is added to the brine well. A second regeneration should follow after treating the resin with soda ash to fully convert the resin to the chloride form.

If the soda ash method fails to clean the resin, a chlorine treatment can be used as a last resort. This method is not recommended because it is extremely harsh on the resin. Fill the brine well with four to eight ounces of household bleach and set the system to regenerate. If a chlorine odor is detected in the drain line, shut down the system for one to two hours. After the system has soaked, complete the rest of the regeneration cycle. To eliminate any remaining chlorine, a second regeneration should be performed. Note that ion exchange resin is not chlorine resistant. If this treatment proves unsuccessful, replacement must be considered.

Before attempting any cleaning procedure, regenerate the bed with salt if the unit contains both cation and anion. Due to high pH or oxidation, any metals, such as iron, will precipitate on the cation resin.

SERVICE CYCLE
Tannin removal utilizing anion exchange resins combines both ion exchange and an absorption process. Tannins, having a slight negative charge, are exchanged for chloride in the resin. The regeneration of anion resin involves the use of salt (NaCl). Generally, the resin is brined at a rate of approximately 10 pounds of salt per cubic foot. Regular regeneration is crucial, with a recommended frequency of every two to three days. Notably, the anion resin is less dense than cation resin.

Backwashing of an anion resin should be conducted at a different flow rate compared to a cation-softening resin. A flow rate of about two gpm/sf is recommended for anion backwashing. Frequent regenerations are effective in reducing organic fouling.

Tannin resin is a residual by-product of anion resin, and the amine concentration is typically low, with an odor threshold around 40 parts per billion. Mixing ammonia and chlorine can create an environment that breaks down the resin, elevating the pH due to ammonia. If the Total Dissolved Solids (TDS) levels in the influent water exceed 800 ppm, a salty taste may be detected. The use of Reverse Osmosis (RO) is necessary to reduce TDS and eliminate the salty taste.

OTHER METHODS OF REMOVING TANNINS
Chlorine and other oxidizing agents prove effective in breaking down organic compounds like tannins. Conducting a simple jar test can determine the concentration and required time for oxidizing tannins. Post the retention tank, an activated carbon unit can eliminate chlorine and potentially adsorb other organic compounds in the water. Some types of activated carbon may independently reduce tannins to acceptable levels; for the appropriate carbon type, consult your carbon manufacturer. It's important to note that the reaction between chlorine and tannins may generate carcinogenic trihalomethanes (THMs).

Another successful method for tannin removal is reverse osmosis. However, tannins have a tendency to foul the system's membrane in this process. Installing a whole-house reverse osmosis system for comprehensive water treatment can be quite costly. For more information, consult your local water expert.

SAFETY
Caution should be exercised when handling the corrosive acid and alkali solutions used for regeneration to prevent contact with eyes and skin. Goggles and gloves are recommended throughout the entire process. When utilizing oxidizing agents, follow necessary safety precautions to prevent accidents and damage to the resin.

STORAGE
Ion exchange resins should be stored in a cool, shaded place, maintaining a moist environment. The recommended temperature range is between 20 and 40 degrees Celsius. Regularly inspect the resin, add clean demineralized water if needed, and ensure it remains completely moist. Never allow the resin to dry out. Always store the resin drum in the shade.

MAIN PURPOSE
Primarily used for water purification, wastewater treatment, biological products, and the hydrometallurgy of tungsten and molybdenum extraction.

OTHER USES
Additional applications include water softening, desalination of water preparation, preparation of pure water, and high water. Also employed in amino acid extraction and purification, extraction and purification of antibiotics, extraction and removal of heavy metal ions, separation and purification of rare earth elements, and organic synthesis reactions such as hydrolysis and acid esterification catalyst.

SPECIFICATIONS

• Size: 4.5" x 19 7/8", designed to fit Big Blue filter housings
• Resin Content: Contains 5.5-6.5 lbs of resin, depending on the media
• Operating Temperature Range: 40°F-125°F
• Operating Pressure Range: 40-80 PSI
• Minimum Operating Pressure: Maintain 60 PSI to avoid a drop in home water pressure

All filters are individually wrapped; store the product in a closed bag and keep it moist to prevent dryness. Avoid direct sunlight, and store the product at room temperature (40 to 75 Fahrenheit).

Caution: To prevent rapid buildups in the pre-woven filter and ensure the Nitrate filter's longer lifespan without quick clogging and a subsequent drop in pressure throughout your entire home, always install this filter after the sediment filter.

Additionally, it is recommended to follow this filter with either a CTO or GAC carbon filter to effectively combat any unpleasant odors that may arise during the Tannin-to-Chloride exchange. Without a carbon filter after the Tannin filter, there is no effective way to address the issue of foul odors.

Anion Resin for Tannin Reduction - 5 lbs Bag

A High Capacity Anion Exchange Resin for Domestic Applications

NOTE: Five pounds of resin is enough to refill a 20" x 4.5" refillable filter (for standard 20" housing) about 1 time.

Utilize our potent strong base anion resin to effectively diminish and eliminate tannins from your incoming water supply. Available in bulk bags for convenient refilling of filter cartridges (sold separately). If you're dealing with well water or experiencing persistent brown discoloration that standard sediment or Iron/Manganese filters can't address, consider an anion filter as a potential solution.

Tannins, known for their astringent and bitter taste, are plant polyphenols that bind and precipitate proteins. In the context of water treatment, the term refers to the brown discoloration caused by decaying organic matter, often present in well waters due to the formation of tannins from humic acid. This acid, a complex mixture resulting from the biodegradation of organic matter, contains carboxyl and phenolate groups.

Primary Uses:

• Water purification
• Wastewater treatment
• Biological product processing
• Hydrometallurgy of tungsten
• Molybdenum extraction

Other Applications:

• Water softening
• Desalination of water preparation
• Preparation of pure water and high water
• Amino acid extraction and purification
• Extraction and purification of antibiotics
• Extraction and removal of heavy metal ions
• Separation and purification of rare earth elements
• Organic synthesis reactions, acting as a hydrolysis and acid esterification catalyst.

Tannin Removal

• Addressing tannin removal has posed a challenge for some dealers, with standard strong base macroporous anion resins, crafted from styrene and divinylbenzene, traditionally employed until several years ago. Although effective in certain regions, this resin type encountered limitations in others. Over the past five to ten years, the residential water market has witnessed the introduction of more successful resins, making the tannin removal application more appealing to water treatment dealers.
• Softening the water before the tannin removal unit is often recommended. This step ensures the elimination of hardness and metals like iron, which could potentially compromise the performance of the anion resin. Tannins, however, can pass through softening (cation) resin without adverse effects. When hardness levels exceed 10 grains entering the tannin removal unit, there's a risk of precipitating calcium carbonate, forming a white floc that may impede system flow and obstruct exchange sites on the resin. Additionally, metals like iron can foul the anion resin, diminishing its ability to remove tannins. Methods for cleaning these foulants will be discussed later.
• Tannins, large molecular-weight organic compounds resulting from plant and animal decomposition, primarily exist in surface waters or shallow wells. Two main categories of tannins are Humic acid and Fulvic acid, each exhibiting varying structures depending on the vegetation in a given area. Tannins can impart a yellow to dark tea color to water, affecting taste and odor. While not directly regulated, a secondary drinking water standard of 15 alpha units for color exists, although it is not federally enforced. Although not posing health concerns, tannins are aesthetically displeasing.
• Dealing with tannins in water can be challenging, with treatment methods varying in effectiveness based on location and vegetation. While styrene-based macroporous anion resin has traditionally been used for tannin removal, acrylic-based resins have recently emerged, providing excellent results in most cases. These resins can be manufactured as gels or with macroporosity, and low crosslinked/high water retention styrene-based resins have also proven successful in some applications.

If your well water exhibits a slight yellow or brown tint, adding one pound per inch in diameter to your media tank typically restores clarity to the water. For darker water resembling iced tea, you may require up to two pounds per inch in diameter of your media tank.

Although there's mention of using a separate tank solely for tannin removal, our approach involves directly introducing these beads into the existing tank, on top of the regular ones in the water softener, without removing any beads.

To assess the "color" or "tannins," run the water at the well for a brief period, then promptly take a sample in a white cup, bucket, or clear glass. Observe the color immediately before the iron has a chance to react with the air (oxygen). Only if color is present when water is initially drawn would the additional tannin removal resin be deemed necessary alongside your regular softening resins.

Application - Organics; Tannin Removal and Demineralization - Demonstrates excellent resistance to fouling.

Here is some general information on estimating the approximate level of tannins in your water.

Service Cycle Overview:

• The process of tannin removal using anion exchange resins involves a dual mechanism of ion exchange and absorption. Tannins, possessing a slightly negative charge, are exchanged for chloride ions on the resin. Additionally, it is believed that the anion resin can absorb organic compounds. Regeneration of the anion resin is achieved using salt, typically brined at around 10 lbs per cubic foot of salt (NaCl). Regular regeneration is crucial to maintaining resin efficacy.
• Once tannins are exchanged or absorbed onto the resin, they tend to migrate into the inner matrix of the resin bead. Timely regeneration, ideally every two to three days, is essential. Frequent regenerations decrease the likelihood of organic fouling, while extended intervals promote fouling, regardless of whether the anion resin is acrylic or styrene-based.
• The incorporation of tannin resin with softening resin is a common practice, optimizing equipment space and reducing system costs. However, during regeneration, salt may displace calcium from the cation resin and potentially alkalinity from the anion/tannin resin, leading to calcium carbonate precipitation. Indicators of precipitation include a white precipitate in the resin bed, a coating on the drain line, a pressure drop through the system, or a milky-white substance in the backwash water. Cleaning methods will be discussed later.
• Anion resin, with lower density compared to cation resin, requires a distinct backwash flow rate. While the backwash flow rate for cation-softening resin is approximately five gpm/square foot (sf) of area, the anion should be backwashed at around two gpm/sf. In dual bed systems combining softening and tannin removal resins, backwash adjustments or the use of an upper screen or basket in the valve prevent resin loss.
• Tannin resin is often associated with a fishy odor, attributed to the release of an amine by-product from the anion resin. Although the amine concentrations are generally low, the odor threshold is around 40 parts per billion, causing aesthetic displeasure. The fishy odor is more prevalent when water is chlorinated and has a high pH (>8), often occurring with the use of chloramines as a disinfectant. It is advisable to remove any oxidant (chlorine, chloramine, or peroxide) before the anion unit.
• As water passes through a chloride-form anion resin, alkalinity is removed, leading to a decrease in pH. The anion resin has a limited capacity for alkalinity, causing a brief pH decrease during the service cycle. The treated water's chloride content increases, and it is essential to check local water treatment regulations for any chloride limits. Chlorides have a secondary drinking water standard of 250 ppm. If influent water TDS levels exceed 800 ppm, a salty taste may be detected in the treated water, necessitating the use of reverse osmosis (RO) to reduce TDS and eliminate the salty taste.

Methods of Cleaning:

• To address calcium carbonate precipitation, a weak acid such as citric or phosphoric acid proves effective. Compatibility with the unit and associated plumbing is essential when selecting a cleaning agent, and this method is generally suitable for treating various types of metal fouling.
• When tannin color passes through a previously functioning unit, an attempt to clean the resin is warranted. For this, soda ash (Na2CO3) can be introduced into the brine to aid in cleaning the anion resin. Typically, 0.5 to 1 pound of soda ash is added to the brine well. The soda ash elevates the pH of the brine, causing the resin to swell further, enlarging the pores for enhanced elution of tannins. Additionally, tannins are more soluble at higher pH levels, creating an environment conducive to stripping them from the resin. Note that this cleaning process may result in the fishy odor. After treating the resin with soda ash, a second regeneration should be conducted to completely convert the resin to the chloride form.
• If soda ash proves ineffective in cleaning the resin, chlorine treatment can be employed as a last resort. Introduce approximately four to eight ounces of standard household bleach into the brine well and initiate the regeneration process. Once a chlorine odor is discernible in the drain line, pause the system for one to two hours, and resume the remainder of the regeneration cycle after the soak. A second regeneration is necessary to eliminate any residual chlorine. It's crucial to recognize that this cleaning procedure is harsh on the resin and should be considered a final option. Oxidants like chlorine can break down ion exchange resin, and although there is no resin on the market that is entirely chlorine-resistant, some are more chlorine-tolerant. The tannin resins in today's water treatment market are relatively chlorine-intolerant. If this treatment proves unsuccessful, replacement should be contemplated.
• If the unit houses both cation and anion, it is advisable to regenerate the bed with salt before attempting any cleaning procedure. Metals, such as iron, may precipitate on the cation resin due to high pH or oxidation.

Alternative Approaches to Tannin Removal:

• Oxidizing agents, such as chlorine, prove effective in breaking down organic compounds like tannins. A simple jar test can reveal the concentration and retention time needed to oxidize tannins. Following the retention tank, an activated carbon unit can eliminate chlorine and potentially adsorb other organic compounds in the water. Certain types of activated carbon alone may also reduce tannin levels to acceptable thresholds. It is crucial to consult with your carbon manufacturer to identify the most suitable product. It's worth noting that the reaction between chlorine and tannins may generate trihalomethanes (THMs), recognized carcinogens.
• Reverse osmosis represents another viable method for tannin removal. Given that tannins are high molecular weight organics, reverse osmosis should effectively reject them. However, tannins may pose a challenge by fouling the membrane in the system. Additionally, installing a whole-house reverse osmosis system to treat all water can be prohibitively expensive. For detailed information, it is recommended to consult with your local water expert.

Conclusion:

• Historically, tannin removal predominantly relied on carbon- and styrene-based ion exchange resins. However, recent advancements in water treatment have introduced acrylic-based and high water retention/low crosslinked styrene-based anion exchange resins to the residential market, demonstrating superior performance in tannin removal compared to traditional ion exchange resins. While no resin achieves 100 percent effectiveness, these newer resins have significantly enhanced success rates. If you haven't attempted tannin treatment recently, it might be worth exploring again. For any new water treatment application or product, conduct pilot testing with several systems in the field. Once the pilot study validates the effectiveness in a specific area, pursue the business.

Storage:

• Proper care is essential for ion exchange resins throughout their storage. Prevent the resins from drying out by regularly inspecting their condition when stored in plastic bags. If the resin is not moist, add sufficient clean demineralized water to maintain a consistently moist state. Store the resin drum in a shaded area, and the recommended storage temperature falls between 20°C and 40°C.

Safety:

• Exercise caution with acid and alkali solutions used for regeneration, as they are corrosive and should be handled to prevent eye and skin contact. When utilizing oxidizing agents, adhere to necessary safety precautions to prevent accidents and potential damage to the resin.